About Decarboxylation
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On this page we’ll cover decarboxylation, most often encountered during the context of your lack of CO2 from beta-keto acids (and malonic acids) inside the malonic ester synthesis and acetoacetic acid synthesis, respectively.
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Westheimer investigated the rates of decarboxylation in a variety of solvents. If decarboxylation proceeds by way of a charged intermediate, then It could be envisioned that a price acceleration would be observed in solvents using a substantial dielectric regular.
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An additional context where by decarboxylation comes up is in retro Diels-Alder reactions of pyrones. Cure of pyrones that has a dienophile like electron-lousy alkynes followed by a retro Diels-Alder brings about a loss of CO2 furthermore a whole new aromatic ring.